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Since the lifetime of O 2 ( 1 Δ g ) in acetonitrile is much lower than in CCl 4 (5.0–8.0 × 10 −5 s and 0.02–0.08 s, respectively), the TMD/O 2 ( 3 Σ g − ) NIR light emission in acetonitrile was very low under similar experimental conditions 61,62
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